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Nia Moseby - Vance and Nia first meet when Nia kicks Vance and puts blue paint all over his face when trying to protect Zack. Vance thinks Nia is cute and the way she stood up to him was "awesome". They started dating some time after "First Day of High School". They continued to date until Vance dumped Nia for Dana Wohl because Dana was a cheerleader in "Benchwarmers".
Zack Martin - Vance does not like Zack at all. At their first meeting, Zack had his arm around Vance's then-girlfriend Amber. They later meet again in detention.
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